(S,L,J)-мультиплст
4/»а
>F>n
4/v,
4Ч
4Ч
4%
*ч .
vv. + f*v.
‘Ч
•н.ч,
“Ч
'в ч.
Ч » и + 2С»Л + 4GVs
a* .v, + 4(?1>Л + 4<?»/.
27Ч
гч
ап
и Чш
Ч
ч ,
%•
lJ’l,
Энергия штаркоБСшгх уровней, см-1
300 к
о, 130, 240, 487, 612
1914, 2066, 2083, 2275, 2318, 2405
3835, 3990*, 4004, 4225, 4267, 4320, 4383
11340, 11555
Кристалл NaGdGeO/., 77 К [92, 93]
0, 135, 235, 468, 607
1914, 2056, 2070, 2266, 2311, 2397
3838, 4002 *, 4007 *, 4217, 4264, 4364, 4382
5745, 5920, 5981, 6245, 6305, 6403, 6433, 6518
11346, 11561
12 344*, 12 475, 12520, 12 558, 12 639, 12699, 12 767, 12 807
13 313, |
|
13 472, |
13 533, |
13 557, |
|
13564*, |
|||
13 639 |
|
|
|
|
|
|
|
|
|
14556, |
|
14 658, |
14 722, |
14 921, |
|
14 997 |
|||
15 848, |
|
15 877, |
16 048, |
16 090, |
16 129 |
||||
16811, |
|
17 036, |
17084 |
|
|
|
|
|
|
17 180, |
17 311, |
17465, |
17 515 |
|
|
|
|||
18 680, |
18 815, |
18 926, |
19 026*, |
19 045*, |
|||||
19 057*, |
19091*, |
19 261, |
19356, |
19413, |
|||||
19 427, |
19 556, |
19618, |
19 638 |
|
|
|
|||
19 858, |
19 908, |
20015, |
20 262, |
20 661, |
|||||
20 670 *, 20 859, 20 932, 21045, |
21 070, |
||||||||
21 135, |
21 198, |
21 233, |
21445, |
21487, |
|||||
21 643, |
21 769, |
21 968, |
22 018 |
|
|
|
|||
22 314 *, 22 448
23 176
23 531, 23 817, 23 846
300 К
0, 135, 231, 481, 602
1916, 2057, 2070, 2265, 2311, 2393
3837, 3999, 4002, 4208, 4254, 4309, 4374
11337, 11552
Кристалл NaLuGeOt, 77 К [92, 93]
0, 140, 261, 510, 637
1919, 2080, 2093, 2297, 2339, 2424
Количество
уровней
|
|
ЛЕ, см-1 |
теор. |
эксп. |
|
5 |
5 |
612 |
6 |
6 |
490 |
7 |
7 |
548 |
2 |
2 |
215 |
5 |
5 |
607 |
6 |
6 |
483' |
7 |
7 |
544 |
8 |
8 |
773' |
2 |
2 |
215 |
8 |
8 |
(463*) |
6 |
6 |
(326) |
5 |
5 |
441 |
6 |
5 |
281* |
3 |
3 |
273 |
4 |
4 |
335 |
16 |
14 |
(959 *) |
19 |
19 |
(2160 *) |
2 |
2 |
134* |
1 |
1 |
— |
3 |
3 |
315 |
5 |
5 |
602 |
6 |
6 |
477 |
7 |
7 |
537 |
2 |
2 |
215 |
5 |
5 |
637 |
6 |
6 |
505 |
4/,v .
-мультиллет
' Ч ,
'Ч г
*ч .
4Ч >
« ч .
4Ч
АЧ .
лч >
* Ч ш
АЧ г
4Ч .
* 4 *
4Ч
4Ч
4Ч
4S . + (2G>
(*с. 4G)T/j
гч
4Ч 2(Л Я).д
*G UJt
*ч>
i D >u
*<Л D ) . f ,
4 /v ,
4/“/.
* 4 .
' Ч ,
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Количество |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
уровней |
|
|
|
Энергия штарковских уровней, см -1 |
|
|
АЕ%См-1 |
|||||||||||||||||
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
теор. |
эксп. |
|
3836, 4018 *, 4023 *, 4224, 4284 *, |
4339, |
7 |
7 |
568 |
|||||||||||||||||
4404 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
5740, |
5930, |
|
6000, |
6275, |
6325, |
6425, |
6560, |
8 |
8 |
805 |
|||||||||||
6545 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
11 356, |
И 553 |
|
|
|
|
|
|
|
|
|
|
|
2 |
2 |
197 |
||||||
|
|
|
|
|
|
|
300 К |
|
|
|
|
|
|
|
|
|
|
|
|||
1920, 2075, 2088 *, 2292, 2334, 2417 |
|
|
6 |
6 |
497 |
||||||||||||||||
11350, |
11550 |
|
|
|
|
|
|
|
|
|
|
|
2 |
2 |
200 |
||||||
Кристалл KY(MO0 4)2, 77 К [95] |
|
|
|
|
|
|
|||||||||||||||
0, |
94, |
162, |
253, |
430 |
|
|
|
|
|
|
|
|
5 |
5 |
430 |
||||||
1960, 1985, 2016, 2079, 2120, 2205 |
|
|
|
6 |
(> |
245 |
|||||||||||||||
'3810, |
3865, |
|
3904*, |
3940, |
4030, |
|
4110, |
4195 |
7 |
7 |
385 |
||||||||||
5750, |
5820, |
|
|
5890*, |
5930, |
6000, |
|
6180*, |
8 |
8 |
540* |
||||||||||
6230, |
6290* |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|||||
11356, |
11438 |
|
|
|
|
|
|
|
|
|
|
|
2 |
2 |
82 |
||||||
12 369, |
12 423, |
12 459 |
|
|
|
|
|
|
|
|
3 |
3 |
90 |
||||||||
12 492, |
12 545, |
12 590, |
12 642, |
|
12 670 |
|
5 |
5 |
178 |
||||||||||||
13 215, |
13 310, |
13 387, |
13435 |
|
|
|
|
|
|
4 |
4 |
220 |
|||||||||
13 479, |
13 488 |
|
|
|
|
|
|
|
|
|
|
|
2 |
2 |
9 |
||||||
14 576, |
14 629, |
14 698, |
14 727, |
|
14 760 |
|
5 |
5 |
184 |
||||||||||||
15 798, |
15 835, |
15 853, |
15 923, |
|
15 970, |
|
6 |
6 |
197 |
||||||||||||
15 995 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
||
16 866, |
16 909, |
16 966, |
17 065, |
17 185, |
|
7 |
7 |
(498) |
|||||||||||||
17 238, |
17 364 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
||||||
18 702*, |
18 780, |
18 797, |
18 832 |
|
|
|
|
4 |
4 |
130* |
|||||||||||
18 875, |
18 928, |
18 965, |
19 037*, |
19 048 |
5 |
5 |
173* |
||||||||||||||
20 390, |
20400*, |
20 425, |
20483* |
20 505*, |
8 |
7 |
200* |
||||||||||||||
20 535, |
20 590 * |
|
|
|
|
|
|
|
|
|
|
|
|
|
|||||||
20 705, |
20 730, |
20 750, |
20 772, |
20 825 |
|
5 |
5 |
120 |
|||||||||||||
20 842, |
20 860 |
|
|
|
|
|
|
|
|
|
|
|
2 |
2 |
18 |
||||||
20 910, |
20 995, |
21 026, |
21093, |
21 128, |
|
6 |
6 |
300 |
|||||||||||||
21 210 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
||
23 105 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
1 |
1 |
— |
||
23 580, |
23 685 :, |
23 752 * |
|
|
|
|
|
|
3 |
3 |
172* |
||||||||||
25 915 *, |
25 975 |
|
|
|
|
|
|
|
|
|
|
2 |
2 |
60* |
|||||||
Кристалл KY(WOt)2, 77 К [96, 97] |
|
|
|
|
|||||||||||||||||
0, |
104, |
155, |
306, |
355 |
|
|
|
|
|
|
|
|
5 |
5 |
355 |
||||||
1943, |
1959, |
|
2020, |
2112, |
2142, |
|
2180 |
|
|
6 |
6 |
237 |
|||||||||
3902, |
3916, |
|
3975, |
4077, |
4100, |
|
4145 |
|
|
7 |
7 |
273 |
|||||||||
5860, 5874, 5952, 5963 *, 6074, 6192, |
|
8 |
8 |
427 |
|||||||||||||||||
6240, |
6287 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|||
—
(S ,L ,J )- мультиплет
4/\,
*РчЛ * н >и
4^ /. + 45за
*F;.
*нй/г
*Gljt + (*G, *G),h
(2G .4G),/s
iG4>
*к„и
iG»ji + 4G11/=
**Чш
2pv,
ю ч>
V V.
iD‘h
A4
44
44
4/‘V*
4pv.
4 4 ,
44
4 и/,
4
4pv ,
4р‘/ , + ая . /г
4pv , + V ./.
1д а /.
|
|
|
|
|
|
|
|
|
|
|
|
Количество |
||
|
|
|
|
|
|
|
|
|
|
|
|
уровней |
||
|
Энергия штарковских уровней, см -1 |
|
|
|
||||||||||
|
|
|
|
|
|
|
|
|
|
|
|
теор. |
|
эксп. |
11300, |
11412 |
|
|
|
|
|
|
|
2 |
|
2 |
|||
12 324, |
12 398, |
12 425, |
12 464, |
12527, |
8 |
|
8 |
|||||||
12 560, |
12 601, |
12 636 |
|
|
|
|
|
6 |
|
6 |
||||
13277, |
13 348 *, |
13 367, |
13 403, |
13 441, |
|
|||||||||
13454 |
|
|
|
|
|
|
|
|
|
5 |
|
5 |
||
14 545, |
14 567, |
14 636, |
14 743, |
14785 |
|
|||||||||
15 756, |
15 780, |
15 838, |
15 896, |
15 950, |
6 |
|
6 |
|||||||
15 968 |
|
|
|
|
|
|
|
|
|
7 |
|
7 |
||
16 792, |
16 903 *, |
16 929, |
17 047, |
17 112 *, |
|
|||||||||
17 224, |
17 301 |
|
|
|
|
|
|
|
|
|
4 |
|||
18 755, |
18 793, |
18847, |
18 936 |
|
|
|
4 |
|
||||||
19138, |
19 290*, |
19324, |
19354, |
19 387 |
5 |
|
5 |
|||||||
19 474, |
19 535, |
19558, |
19 600, |
19 662, |
7 |
|
6 |
|||||||
19818* |
|
|
|
|
|
|
|
|
|
|
|
|||
20 768, |
20 815, |
20844, |
20 859, |
20 920, |
11 |
|
9 |
|||||||
20 982, |
21 042, |
21090, |
21133 |
|
|
|
|
|
|
|||||
21 249, |
21 418, |
21455, |
21 608, |
21678, |
8 |
|
6 |
|||||||
21 834 |
|
|
|
|
|
|
|
|
|
|
|
|
||
23 041 |
|
|
|
|
|
|
|
|
|
1 |
|
1 |
||
23 504, |
23 652, |
23 717 |
|
|
|
|
|
3 |
|
3 |
||||
25 917, |
26 025 |
|
|
|
|
|
|
|
2 |
|
2 |
|||
27 581, |
27 660 |
|
|
|
|
|
|
|
2 |
|
2 |
|||
27 757 |
|
|
|
|
|
|
|
|
|
|
1 |
1 |
1 |
|
|
Кристалл KNdP40 12, 77 К [98] |
|
|
|
|
|||||||||
0, |
99, |
|
171, |
228, |
338 |
|
|
|
|
|
5 |
|
5 |
|
1952, |
1984, |
2018, |
2040, |
|
2115, |
2146 |
|
6 |
|
6 |
||||
3913, |
3951, |
4025, |
4053, |
|
4130, |
4137, |
4144 |
7 |
|
7 |
||||
5895, |
6266 |
|
|
|
|
|
|
|
|
8 |
|
2 |
||
11474, |
11526 |
|
|
|
|
|
|
|
2 |
|
2 |
|||
Кристалл KGd(W04)2, 77 К [20, 99] |
5 |
|
|
|||||||||||
0, |
102, |
150, |
295, |
340 |
|
|
|
|
|
|
5 |
|||
1943, |
1960, |
2020, |
2105, |
|
2130, |
2172 |
|
6 |
|
6 |
||||
3900, |
3914, |
3970, |
4060, |
|
4087, |
4135, |
4165 |
7 |
|
7 |
||||
5869, |
5882, |
5959, |
6074, |
|
6148, |
6192, |
6239, |
8 |
|
8 |
||||
6288 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
11313, |
11418 |
|
|
|
|
|
|
|
2 |
|
2 |
|||
12 337, |
12343, |
12 406, |
12435, |
12 469, |
8 |
|
8 |
|||||||
12 562, |
12 605, |
12 638 |
|
|
|
|
|
|
|
|
||||
13 289, |
13372, |
13 408, |
13 448, |
13 460 |
6 |
|
5 |
|||||||
14 55S, |
14579, |
14 644, |
14 744, |
14 788 |
5 |
|
5 |
|||||||
15 768, |
15 792, |
15 847, |
15 904, |
15 957, |
6 |
|
6 |
|||||||
15 975 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
А Т71 vX»>p itf— 1
112
(312)
(177)
240
212
(491)
181
248
344*
(365 *)
585*
—
213
108
79
—
338 |
|
194 |
|
231 |
|
СО |
* |
52 |
|
340
229
265
419
105
(301)
(171*)
230
207
8а
(S,L,J)-мультиплет
4G./f + (*G, 0G)7/I
<4?, *C)V.
3Gv ,
**«■/.
4C. / , + 4G«/l
* * . , , + 4>1/e
V V.
‘/а7*
V./«
4ч
4/»л
4/«/.
vv.
vv. + e*v.
v v. + *■/. *Л/.
4c ./i + (* c ,‘C)f/f
(V?. ^)v,
Ъ и
ч+ s ,
■*•/. + вл .,.
v v.
|
|
|
|
|
|
|
|
|
|
|
Количество |
|
|
|
|
|
|
|
|
|
|
|
|
|
уровней |
|
|
|
Энергия штарковских уровней, см -1 |
|
|
AF, см -1 |
|||||||||
|
|
|
|
|
|
|
|
|
|
|
теор. |
эксп. |
|
16 806, |
16 943, |
17 058, |
17 118, |
17 143, |
7 |
7 |
(498) |
||||||
17 226, |
17 304 |
|
|
|
|
|
|
|
|
|
|||
18 770, |
18 810, |
18 859, |
|
18 943 |
|
|
4 |
4 |
173 |
||||
19 212, |
19 297, |
19 332, |
|
19368, |
19 392 |
5 |
5 |
180 |
|||||
19 485, |
19 530, |
19564, |
|
19 600, |
19 651, |
7 |
6 |
319* |
|||||
19 804 * |
|
|
|
|
|
|
|
|
|
|
|
||
20 716, |
20 746, |
20 780, |
|
20 823, |
20 852, |
11 |
11 |
(427) |
|||||
20 867, |
20 923, |
20 992, |
|
21 053, |
21 098, |
|
|
|
|||||
21143 |
|
|
|
|
|
|
|
|
|
|
|
|
|
21261, |
21318, |
21411, |
|
21460, |
21551, |
10 |
9 |
(550 *) |
|||||
21578, |
21 599, |
21 664, |
|
21 811 * |
|
|
|
|
|||||
23 055 |
|
|
|
|
|
|
|
|
|
1 |
1 |
- |
|
23 521, |
23 655, |
23 717 |
|
|
|
|
3 |
3 |
196 |
||||
|
|
|
|
|
300 к |
|
|
|
|
|
|
|
|
1945, |
1956, |
2020, |
2104, |
2134, |
2172 |
|
6 |
6 |
227 |
||||
11315, |
11417 |
|
|
|
|
|
|
2 |
2 |
102 |
|||
Кристалл KLu(WO*h, 77 К [99] |
|
5 |
|
|
|||||||||
0, |
108, |
157, |
324, |
370 |
|
|
|
|
5 |
370 |
|||
1945, |
1962, |
2023, |
2123, |
2155, |
2189 |
|
6 |
6 |
244 |
||||
3894, |
3909, |
3969, |
4079, |
4108, |
4152, |
4179 |
7 |
7 |
285 |
||||
5859, |
5874, |
5951, |
6086, |
6181, |
6207, |
6253, |
8 |
8 |
441 |
||||
6300 |
|
|
|
|
|
|
|
|
|
|
|
|
|
11290, |
11410 |
|
|
|
|
|
|
2 |
2 |
120 |
|||
12 311, |
12 314, |
12 386, |
|
12 416, |
12 456, |
8 |
8 |
(319) |
|||||
12 551, |
12 591, |
12 630 |
|
|
|
|
|
|
|
||||
13 262, |
13 360, |
13 394, |
|
13431, |
13444 |
6 |
5 |
(182 *) |
|||||
14528, |
14 551, |
14 623, |
|
14 736, |
14777 |
5 |
5 |
249 |
|||||
15 744, |
15 785, |
15 825, |
|
15 886, |
15 942, |
6 |
6 |
216 |
|||||
15 960 |
|
|
|
|
|
|
|
|
|
|
|
|
|
16 758, |
16 904, |
17 020, |
|
17 090, |
17 126, |
7 |
7 |
(524) |
|||||
17 206, |
17 282 |
|
|
|
|
|
|
|
|
|
|||
18 725, |
18 765, |
18 818, |
|
18 912 |
|
|
4 |
4 |
(187) |
||||
19162, |
19260, |
19299, |
|
19334, |
19 363 |
5 |
5 |
201 |
|||||
19 452, |
19467, |
19541, |
|
19 585, |
19 648, |
7 |
6 |
359* |
|||||
19811 |
|
|
|
|
|
|
|
|
|
|
|
|
|
20 668, 20 701, |
20 732, |
|
20 780, |
20 811, |
И |
И |
(430) |
||||||
20 825, |
20 889, |
20 947, |
|
21014, |
21054, |
|
|
|
|||||
21 098 |
|
|
|
|
|
|
|
|
|
|
|
||
21 216, |
21 268, |
21 392, |
|
21425, |
21 533, |
10 |
9 |
(604 *) |
|||||
21 556, |
21 592, |
21 655, |
|
21 820 |
|
|
|
|
|
||||
23 015 |
|
|
|
|
|
|
|
|
1 |
1 |
- |
||
23 459, |
23 620, |
23 691 |
|
|
|
|
3 |
3 |
232 |
||||